Ture was stirredas described above. Yield was mgchange and IEM-1460 Purity & Documentation solutionblue mixture.
Ture was stirredas described above. Yield was mgchange and solutionblue mixture. The mL, was purified for 24 h, causing polymer 183 precipitated inand collected by filtration. The1.0 mmol)was resuspendedthechlorobenzene (25 mL), of a dark to violet. The polymer polymer was added, and within a gradual color (73 ) anhydrousto violet powder.mL, 1.0 mmol) was as described above. Yield 183 mg (73 )of your collected by filtration. The solution as a dark violet. The polymer was was resuspended in chlorobenzenecolor modify and answer hydrazine (0.03 polymer purified added, causing a gradual (25 mL), and the solution to violet. powder. item as hydrazine (0.03 polymer was was added, causing gradual color adjust of anhydrous a dark violetThemL, 1.0 mmol)purified as describedaabove. Yield 183 mg (73 ) Table 3. Weight-average molecular resolution to)dark violet powder. was purified of polymerization (Xw ) Yield 183 mg (73 ) solution as a in g/mol and weight-average degree as described above. for polymers the weight (Mw violet. The polymer Table three. by FeCl3 -initiated oxidative polymerization beneath distinctive conditions. Mw of polymerization (Xw) in the synthesized Weight-average molecular weight (Mw) in g/mol and weight-average degreevalues have been determinedfor polymers solution as a dark violet powder.Addition FeCl3 Time (g/mol) Yield Xw Addition FeCl Time (g/mol) 20 20 Reverse Equivalents 2.three 24 24 h h 73 73 6300 w Reverse two.three 3 6300 M Order of Reaction Yield 73 Xw20 Entry Structure Acronym Reverse two.three 24 6300 21 Reverse 1 two.three 24 h 80 5200 3 17 FeCl3 Timeh (g/mol) PEDOT-C12 Addition 1 3 2 2.three 24 h 80 Reverse 5200 Reverse 2.3 5200 1720 17 3 Methyl jasmonate In Vitro Typical 1 2.3 24 h h 26 20,000 3 65 12 Reverse 2.3 2424 h 7380 6300 PEDOT-C12 1 3 Typical 2.three 24 h 26 20,000 three 6517 20,000 65 2.3 5200 32 Common 2.3 2424 h h 26 80 PEDOT-C12 Reverse four Typical 4 24 h 58 231,000 747 three Regular two.three 24 h 26 20,000 65 PEDOT-C12 four four Normal 231,000 747 747 Standard 44 24 h 24 h 58 58 231,000 Reverse 2.3 24 h 42 5200 3 18 five 4 Normal 4 24 h 58 231,000 747 Reverse two.three 24 24 h h h 24 42 78 42 5200 3 three three 18 18 two Reverse two.three 5200 5 56 Normal 2.three 5200 18 PBHOT Typical 78 5200 18 7 Normal 42.3 24 h 11 two 5200 three three three 18 99 28,000 Standard 2.three 242424 h h h 78 two 42 PBHOT Reverse two.three 5200 18 56 six PBHOT Typical 24 11 28,000 99 87 Regular 44 48 h h h 102 28,000 3 9918 90,000 318 six Standard 2.3 5200 Common four 2424 h 11 78 7 PBHOT eight Common 4 48 h 10 90,000 318 9 Reverse 2.three 24 h 75 150,000 904 7 Common four 24 h 11 28,000 99 Standard four 48 h ten 90,000 318 8109 Reverse two.three 24 75 150,000 318 904 Normal two.3 24 h h h 26 81,000 488 8 Typical four 48 10 90,000 P3HT ten Standard two.3 24 h 26 150,000 81,000 904395 488 Normal 4 24 h 25 65,000 Reverse two.three 2424 h h 75 75 9 Reverse two.3 150,000 904 911 P3HT Common 65,000 395 12 Standard four 48 h h 72 65,000 1011 Standard 2.34 2424 h 2625 81,000 81,000 488395 488 Standard 2.three 24 h 26 ten P3HT P3HT 1 12Chloroform was used as a solvent instead of chlorobenzene. 2 Unique work-up process (see experimental section). 3395 Standard 4 48 h 72 65,000 11 Typical four 24 h 25 65,000 395 Entry Structure AcronymStandard 4 24 h 25 65,000 395 11 Beneath the reduce limit of your a solvent alternatively of chlorobenzene. two Unique work-up process (see experimental section). three 1 Chloroform was applied as calibrated area from the analytical column. 12 Common four 48 h 72 65,000 395 Typical four 48 h 72 65,000 395 12 1 Under the reduced limit from the calibrated area from the analytical co.
